I'll answer the easy one first.
Masterwork Weapons:
On the Weapons tab, the first section is "Magic, Custom & Masterwork Weapons".
Click "New Magic, Custom or Masterwork weapon of size: <whatever size your character is>"
Then at the very top of the list, you should see " - Custom / magic weapon". Click that.
Now "Click to Choose Weapon", then check the "Masterwork" box.
Spells:
If you go to the "Personal Tab", you can add permanent adjustments. If you go to the "Adjust" tab, you can add adjustments there as well. These adjustments include spell-casting abilities. It's a cumbersome way to do it, though, because you have to add each spell individually.
You can always opt to create a new class through the editor, but someone besides me would have to help you with that.
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