You can freely mix 32-bit and 64-bit versions of the product with the same data. The only potential gotcha would be with large images and/or having lots of images loaded across numerous tabs concurrently. In 64-bit, that won't be a problem. In 32-bit, Realm Works could run out of memory. But that just limits how much you can have open at one time in a 32-bit installation. The data itself will all work fine.
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